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The INTERNET Database of Periodic TablesThere are hundreds of periodic tables in web space, but there is only one comprehensive database of periodic tables & periodic system formulations. If you know of an interesting periodic table that is missing, please contact the database curator: Dr Mark R Leach.
Periodic Table formulations from the years before 1900, by date:
9000 BCE Discovery of Copper Cu Copper, atomic number 29, has a mass of 63.546 au. Copper had its earliest use in about 9000 BCE, and the oldest sample dates from 6000 BCE. It was discovered by Middle East workers and the earliest sample is from Anatolia. 7000 BCE Discovery of Lead Pb Lead, atomic number 82, has a mass of 207.2 au. Lead had its earliest use in about 7000 BCE, and the oldest sample dates from 3800 BCE. It was discovered by Africa and the earliest sample is from Abydos, Egypt. 6000 BCE Discovery of Gold Au Gold, atomic number 79, has a mass of 196.967 au. Gold had its earliest use in about 6000 BCE, and the oldest sample dates from 4400 BCE. It was discovered by Bulgaria and the earliest sample is from Varna Necropolis. 5000 BCE Discovery of Iron Fe Iron, atomic number 26, has a mass of 55.845 au. Iron had its earliest use in about 5000 BCE, and the oldest sample dates from 4000 BCE from Egypt. 5000 BCE Discovery of Silver Ag Silver, atomic number 47, has a mass of 107.868 au. Silver had its earliest use in about 5000 BCE, and the oldest sample dates from 4000 BCE, and is from Asia Minor. 3750 BCE Discovery of Carbon C Carbon, atomic number 6, has a mass of 12.011 au. Carbon has many allotropes, including: graphite, diamond, graphene, C60, single wall nanotubes, etc. Carbon had its earliest use in about 3750 BCE. It was discovered by Egyptians and Sumerians. 3500 BCE Discovery of Tin Sn Tin, atomic number 50, has a mass of 118.71 au. Tin + copper gives bronze, and so the Bronze Age. Tin had its earliest use in about 3500 BCE, and the oldest sample dates from 2000 BCE. It is unknown who discovered the element. 2000 BCE Discovery of Sulfur (Sulphur) S Sulfur, atomic number 16, has a mass of 32.068 au. Sulfur is a pale yellow, odourless, brittle solid. Sulfur had its earliest use in about 2000 BCE. It was discovered by Chinese/Indians. 2000 BCE Discovery of Mercury Hg Mercury, atomic number 80, has a mass of 200.592 au. Mercury had its earliest use in about 2000 BCE, and the oldest sample dates from 1500 BCE. It was discovered by Chinese/Indians and the earliest sample is from Egypt. 1000 BCE Discovery of Zinc Zn Zinc, atomic number 30, has a mass of 65.38 au. Zinc had its earliest use in about 1000 BCE, and the oldest sample dates from 1000 BCE. It was discovered by Indian metallurgists and the earliest sample is from the Indian subcontinent. 800 BCE Discovery of Antimony Sb Antimony, atomic number 51, has a mass of 121.76 au. Antimony had its earliest use in about 800 BCE. 450 BCE Classical Elements: Earth, Water, Air & Fire The Greek Classical Elements — Earth, Water, Air, Fire [& Aether] — date from 450 BC or so, and persisted throughout the Middle Ages and into the Renaissance, deeply influencing European thought and culture. A Greek text Kore Kosmou ("Virgin of the World" - associated with the Egyptian god Thoth - names the four elements fire, water, air, and earth:
The four elements were used by Hippocrates in describing the human body with an association with the four humours:
Plato characterizes the elements from a list created by the Sicilian philosopher Empedocles called these the four "roots." Plato seems to have been the first to use the term element: 300 BCE Discovery of Arsenic As Arsenic, atomic number 33, has a mass of 74.922 au. Arsenic had its earliest use in about 300 BCE. 1000 Elements Known in the Year 1000 Elements known in the year 1000, taken from this Wikipedia page: 1520 Tria Prima of Alchemy Paracelsus identified three primes, the tria prima, of alchemy which are related to the Law of the Triangle, in which two components come together to produce the third. Philosophically speaking, Mercury is the Mind; Salt is the Will & Wisdom; and Sulphur is Love. The three are components or principles of the Philosopher's Stone, and they work potently to transmute any base metal or character into golden perfection. Without these principles, the coveted Stone is ineffectual in its capacity to change vibratory rates.
1617 Elemental Spheres of Terra (earth), Aqua (water), Aer (air) & Ignis (fire) From the German Photo Library Theosophie & Alchemie, a segment of the macrocosm showing the elemental spheres of terra (earth), aqua (water), aer (air), and ignis (fire), by Robert Fludd: 1624 Ripley Scroll The Ripley Scroll, an illustrated alchemical manuscript, in English and Latin, on vellum, England [perhaps Manchester?] 1624. This item was sold by Christie's in 2017. There are 23 known versions of the Ripley Scroll (or "Ripley Scrowle"). George Ripley (c. 1415-1490) was one of England's most famous alchemists. His alchemical writings attracted attention not only when they were published in the fifteenth century, but also later in the sixteenth and seventeenth centuries. His writings were studied by noted figures such as the alchemist John Dee, Robert Boyle (who is considered to be the first modern chemist), and even Isaac Newton. There is a copy/version of the Ripley Scroll at the British Library. ![]() 1669 Discovery of Phosphorus P Phosphorus, atomic number 15, has a mass of 30.974 au. Phosphorus exists in several allotropic forms including: white, red and black. Phosphorus was first isolated in 1669 by H. Brand. 1671 Valentinus' Table of Chymicall & Philosophicall Charecters A table of alchemical symbols from Basilius Valentinus' (Basil Valentine) The Last Will and Testament: 1682 Digby's A Choice Collection of Rare Secrets 1687 Alchemical Emblem Showing the Four Classical Elements From the German Photo Library Theosophie & Alchemie, a seventeenth century alchemical emblem showing the four classical elements (air, fire, earth & water) in the corners of the image, alongside the tria prima on the central triangle: 1690 Newton's Lapis Philosophicus cum suis rotis elementaribus In 1936 a collection of Newton's papers, amazingly regarded as of "no scientific value" when offered to Cambridge university some fifty years earlier, was purchased at Sotheby's by the respected economist and Newton scholar John Maynard Keynes. Originally left in a stack by Newton when he left his post as the director of the London mint in 1696, these documents had somehow fortuitously escaped the burning of Newton's personal writings arranged after his death, and were discovered two centuries later. Included was a handwritten manuscript entitled Lapis Philosophicus cum suis rotis elementaribus: "The philosophical stone elements with its wheels", Google Translate. Notice how the design below also features in the Ripley Scroll, formulated in the mid-1400s. Newton is known to be influenced by this work: ![]() 1700 Elements Known in the Year 1700 Elements known in the year 1700, taken from this Wikipedia page: 1718 Geoffroy's Affinity Table From Wikipedia, Étienne François Geoffroy's 1718 Affinity Table. At the head of the column is a substance with which all the substances below can combine. 1735 Discovery of Cobalt Co Cobalt, atomic number 27, has a mass of 58.933 au. Cobalt was first isolated in 1735 by G. Brandt. 1748 Discovery of Platinum Pt Platinum, atomic number 78, has a mass of 195.084 au. Platinum was first isolated in 1748 by A. de Ulloa, although it had been used by pre-Colombian Americans. 1751 Discovery of Nickel Ni Nickel, atomic number 28, has a mass of 58.693 au. Nickel was first isolated in 1751 by F. Cronstedt. 1753 Discovery of Bismuth Bi Bismuth, atomic number 83, has a mass of 208.98 au. Bismuth was first isolated in 1753 by C.F. Geoffroy. 1766 Discovery of Hydrogen H Hydrogen, atomic number 1, has a mass of 1.008 au. Hydrogen is the lightest element and by far the most abundant element in the universe: it makes up about about 90% of the universe by weight. Under standard conditions, hydrogen exists as a diatomic molecular gas, H2. Hydrogen was first isolated and identified as an element in 1766 by H. Cavendish, although it was first made in 1500 by Paracelsus. 1771 Discovery of Oxygen O Oxygen, atomic number 8, has a mass of 15.999 au. Oxygen exists as a diatomic molecular gas, O2; in this form it makes up about 20% of the atmosphere. Oxygen was first isolated in 1771 by W. Scheele. 1772 Discovery of Nitrogen N Nitrogen, atomic number 7, has a mass of 14.007 au. Nitrogen exists as a diatomic molecular gas, N2, and in this form it makes up about 78% of the atmosphere by volume. The element seemed so inert that Lavoisier named it azote, meaning "without life". Nitrogen was first isolated in 1772 by D. Rutherford. 1774 Discovery of Chlorine Cl Chlorine, atomic number 17, has a mass of 35.452 au. Chlorine exists as a green diatomic molecular gas, Cl2. Chlorine was first isolated in 1774 by W. Scheele. 1774 Discovery of Manganese Mn Manganese, atomic number 25, has a mass of 54.938 au. Manganese was first observed or predicted in 1774 by W. Scheele and first isolated in 1774 by G. Gahn. 1775 Bergman's Dissertation on Elective Affinities Alchemical symbols in Torbern Bergman's 1775 Dissertation on Elective Affinities, which was translated from Latin to English in 1783 from Google Books: 1778 Diderot's Alchemical Chart of Affinities 1781 Discovery of Molybdenum Mo Molybdenum, atomic number 42, has a mass of 95.95 au. Molybdenum was first observed or predicted in 1778 by W. Scheele and first isolated in 1781 by J. Hjelm. 1782 de Morveau's Table of Chemically Simple Substances de Morveau's table of chemically simple substances (updated with modern representations by Mazurs): 1782 Discovery of Tellurium Te Tellurium, atomic number 52, has a mass of 127.6 au. Tellurium caused great difficulty to the chemists who first tried to develop a periodic table, because it has an atomic weight greater than iodine (126.9). Mendeleev prioritised chemical properties over the anomalous atomic weight data, and correctly classified Te along with O, S, & Se. It was only when nuclear structure and the importance of atomic number was recognised, around 1918, that the issue was explained. Tellurium was first isolated in 1782 by F.-J.M. von Reichenstein. 1783 Discovery of Tungsten W Tungsten, atomic number 74, has a mass of 183.84 au. Tungsten was first observed or predicted in 1781 by W. Scheele and first isolated in 1783 by J. and F. Elhuyar. 1787 Méthode de Nomeclature Chimique By Louis Bernard Guyton de Morveau (1737-1816), Antoine Laurent Lavoisier (1743-1794) , Claude-Louis Berthollet (1748-1822) & Antoine-François de Fourcroy (1755-1809) a book: Méthode de Nomeclature Chimique.
The book lists the several hundred chemicals known at the time, including chemical elements, and it discusses the nomenclature (naming). Although not a periodic table as such, the information contained in this book was state of the art for 1787.
1789 Antoine Lavoisier Antoine Lavoisier produced a list chemical substances, that included the 23 known elements. He also refined the concept as before this time, metals - with the exception of mercury - were not considered to be elements. Wikipedia. A list of 33 simple substances compiled by Lavoisier, from Traité Élémentaire de Chimie, Cuchet, Paris, 1789, p. 192: From Peter van der Krogt's Elementymology & Elements Multidict web site:
1789 Discovery of Zirconium Zr Zirconium, atomic number 40, has a mass of 91.224 au. Zirconium was first observed or predicted in 1789 by H. Klaproth and first isolated in 1824 by J. Berzelius. 1789 Discovery of Uranium U Uranium, atomic number 92, has a mass of 238.029 au. Radioactive element with a very long half-life. Uranium was first observed or predicted in 1789 by H. Klaproth and first isolated in 1841 by E.-M. Péligot. 1791 Discovery of Titanium Ti Titanium, atomic number 22, has a mass of 47.867 au. Titanium was first observed or predicted in 1791 by W. Gregor and first isolated in 1825 by J. Berzelius. 1794 Discovery of Yttrium Y Yttrium, atomic number 39, has a mass of 88.906 au. Yttrium was first observed or predicted in 1794 by J. Gadolin and first isolated in 1842 by G. Mosander. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1798 Discovery of Beryllium Be Beryllium, atomic number 4, has a mass of 9.012 au. Beryllium is a metal with a high melting point. At ordinary temperatures it resists oxidation in air. Beryllium compounds are very toxic. Beryllium was first observed or predicted in 1798 by N. Vauquelin and first isolated in 1828 by F. Wöhler and A. Bussy. 1798 Discovery of Chromium Cr Chromium, atomic number 24, has a mass of 51.996 au. Chromium was first observed or predicted in 1797 by N. Vauquelin and first isolated in 1798 by N. Vauquelin. 1800 Elements Known in the Year 1800 Elements known in the year 1800, taken from this Wikipedia page: 1801 Discovery of Niobium Nb Niobium, atomic number 41, has a mass of 92.906 au. Niobium was first observed or predicted in 1801 by C. Hatchett and first isolated in 1864 by W. Blomstrand. 1802 Discovery of Tantalum Ta Tantalum, atomic number 73, has a mass of 180.948 au. Tantalum was first isolated in 1802 by G. Ekeberg. 1803 Dalton's Postulates About The Elements Around the year 1803 in Manchester, John Dalton gave a series of lectures in which he presented his postulates:
From a very early notebook from around this time: 1803 Discovery of Palladium Pd Palladium, atomic number 46, has a mass of 106.42 au. Palladium was first isolated in 1803 by H. Wollaston. 1803 Discovery of Cerium Ce Cerium, atomic number 58, has a mass of 140.116 au. Cerium was first observed or predicted in 1803 by H. Klaproth, J. Berzelius, and W. Hisinger and first isolated in 1838 by G. Mosander. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1803 Discovery of Osmium Os Osmium, atomic number 76, has a mass of 190.23 au. Osmium was first isolated in 1803 by S. Tennant. 1803 Discovery of Iridium Ir Iridium, atomic number 77, has a mass of 192.217 au. Iridium was first isolated in 1803 by S. Tennant. 1804 Discovery of Rhodium Rh Rhodium, atomic number 45, has a mass of 102.906 au. Rhodium was first isolated in 1804 by H. Wollaston. 1807 Discovery of Sodium Na Sodium, atomic number 11, has a mass of 22.99 au. Sodium is a Group 1 element, and these are often referred to as the "alkali metals". Sodium was first isolated in 1807 by H. Davy. 1807 Discovery of Potassium K Potassium, atomic number 19, has a mass of 39.098 au. Potassium is a Group 1 element, and these are often referred to as the "alkali metals". Potassium was first isolated in 1807 by H. Davy. 1808 Dalton's Elements Two pages from John Dalton's A New System of Chemical Philosophy in which he proposed his version of atomic theory based on scientific experimentation (see the scanned book, page 219):
1808 Discovery of Boron B Boron, atomic number 5, has a mass of 10.814 au. Boron has properties that are borderline between metal and non-metal (semimetallic). Boron was first observed or predicted in 1808 by L. Gay-Lussac and L.J. Thénard and first isolated in 1808 by H. Davy. 1808 Discovery of Magnesium Mg Magnesium, atomic number 12, has a mass of 24.306 au. Magnesium is a Group 2 element, and these are called: "alkaline earth metals". Magnesium was first observed or predicted in 1755 by J. Black and first isolated in 1808 by H. Davy. 1808 Discovery of Calcium Ca Calcium, atomic number 20, has a mass of 40.078 au. Calcium is a Group 2 element, and these are called: "alkaline earth metals". Calcium was first isolated in 1808 by H. Davy. 1808 Discovery of Strontium Sr Strontium, atomic number 38, has a mass of 87.62 au. Strontium is a Group 2 element, and these are called: "alkaline earth metals". Strontium was first observed or predicted in 1787 by W. Cruikshank and first isolated in 1808 by H. Davy. 1808 Discovery of Barium Ba Barium, atomic number 56, has a mass of 137.327 au. Barium is a Group 2 element, and these are called: "alkaline earth metals". Barium was first observed or predicted in 1772 by W. Scheele and first isolated in 1808 by H. Davy. 1811 Discovery of Iodine I Iodine, atomic number 53, has a mass of 126.904 au. Iodine exists as a black diatomic molecular solid, I2. Iodine was first isolated in 1811 by B. Courtois. 1813 Wollaston's Slide Rule of Chemical Equivalents Philosophical Transactions: A Synoptic Scale of Chemical Equivalents by William Hyde Wollaston, M.D. Sec. R.S. – or from here – has a diagram for a slide rule of chemical equivalents: Wollaston writes:
Read more in an entry concerning chemical slide rules.
1813 Wollaston's Synoptic Scale of Chemical Equivalents Philosophical Transactions: A Synoptic Scale of Chemical Equivalents by William Hyde Wollaston, M.D. Sec. R.S., or from here. It is apparent that chemistry the years 1810 to 1850 was largely concerned with discovering the whole number stoichiometric ratios of atoms in chemical compounds. Wollaston writes in the text above:
Mark Leach writes:
Interestingly, Wollaston's analysis is far better than Daubeny's 1831 data seen in Oxford. Read more in an entry concerning chemical slide rules.
1814 Wollaston's Physical Slide Rule of Chemical Equivalents From the Science Museum in the UK collection, the Wollaston slide rule of chemical equivalents:
Wollaston uses a decimal scale in which oxygen is defined as having an atomic weight (relative atomic mass) of 10.00 rather than the modern value of 15.999.
![]() Mark Leach writes:
1817 Discovery of Lithium Li Lithium, atomic number 3, has a mass of 6.968 au. Lithium is a reactive metal, of low density: it is the least dense metal. Lithium was first observed or predicted in 1817 by A. Arfwedson and first isolated in 1821 by W. T. Brande. 1817 Discovery of Selenium Se Selenium, atomic number 34, has a mass of 78.971 au. Selenium was first isolated in 1817 by J. Berzelius and G. Gahn. 1817 Discovery of Cadmium Cd Cadmium, atomic number 48, has a mass of 112.414 au. Cadmium was first isolated in 1817 by S. L Hermann, F. Stromeyer and J.C.H. Roloff. 1824 Discovery of Silicon Si Silicon, atomic number 14, has a mass of 28.085 au. Silicon makes up 25.7% of the earth's crust, and after oxygen is the second most abundant element. Silicon was first isolated in 1823 by J. Berzelius. 1825 Discovery of Aluminium (Aluminum) Al Aluminium (aluminum), atomic number 13, has a mass of 26.982 au. Aluminum is a silvery-white metal. Aluminium was first isolated in 1825 by H.C.Ørsted. 1825 Discovery of Bromine Br Bromine, atomic number 35, has a mass of 79.904 au. Bromine exists as an orange diatomic molecular liquid, Br2. Bromine was first isolated in 1825 by J. Balard and C. Löwig. 1829 Döbereiner's Triads Johann Döbereiner found triads: a sequence of three similar elements, where the middle element has a mass equal to the average of the least and most massive. A brief biography can be found on the Nature website. Döbereiner writes in An Attempt to Group Elementary Substances according to Their Analogies (in English)
![]() The diagram below uses mid-nineteenth century atomic mass information rather than modern data. If atomic numbers (Z) are used (a property unknown in 1850), the triads are exact: 1829 Discovery of Thorium Th Thorium, atomic number 90, has a mass of 232.038 au. Radioactive element with a very long half-life. Thorium was first observed or predicted in 1829 by J. Berzelius and first isolated in 1914 by D. Lely, Jr. and L. Hamburger. 1830 Discovery of Vanadium V Vanadium, atomic number 23, has a mass of 50.942 au. Vanadium was first observed or predicted in 1801 by M. del Río and first isolated in 1830 by N.G.Sefström. 1831 Daubeny's Teaching Display Board & Wooden Cubes of Atomic Weights The Museum of the History of Science, Oxford, has a display of Charles Daubeny's teaching materials, including a black painted wooden board with "SYMBOLS OF SIMPLE BODIES": showing symbols, atomic weights and names of elements in two columns, and a small pile of cubes with element symbols.
From the HSM Database (Inventory no. 17504):
The period from 1810 to 1860 was crucial in the development of the periodic table. Most of the main group and transition elements had been discovered, but their atomic weights and stoichiometries (combining ratios) had not been fully deduced. Oxygen was assumed to have a weight of 6, and consequently carbon is assumed to have a mass of 6. Daubeny's element symbols and weights – along with the modern mass data – are tabulated:
While quite a number of weights are close to the modern values, many are way out. However, the error is usually a stiotoimetric factor error. From the HSM Database (Inventory no. 33732): SET OF WOODEN CUBES ILLUSTRATING ATOMIC WEIGHTS Forty-two wooden cubes numbered 1-42, painted black with symbols for certain elements, compounds or radicals painted in white on the faces, together with the corresponding atomic, molecular or radical weights. The face markings appear in various combinations:
A typical cube (no. 3) may be represented by the following figure. They present something of an enigma as their faces do not form an obvious pattern. The numbers indicate that there were 42 cubes. In style they are similar to the figures on the panel of atomic weights. The cubes are listed in Daubeny's 1861 catalogue, p. 11 as: "Wooden cubes for illustrating atomic weight". [See D. R. Oldroyd, The Chemical Lectures at Oxford (1822-1854) of Charles Daubeny, M.D., F.R.S. Notes and Records of the Royal Society, vol. 33 (1979), pp. 217-259.]
1836 Berzelius' Electronegativity Table Berzelius' electronegativity table of 1836. The most electronegative element (oxygen or Sauerstoff) is listed at the top left and the least electronegative (potassium or Kalium) lower right. The line between hydrogen (Wasserstoff) and gold seperates the predomently electronegative elements from the electropositive elements. Page 17 and ref. 32 from Bill Jensen's Electronegativity from Avogadro to Pauling Part I: Origins of the Electronegativity Concept, J. Chem. Educ., 73, 11-20 (1996): 1838 Discovery of Lanthanum La Lanthanum, atomic number 57, has a mass of 138.905 au. Lanthanum was first observed or predicted in 1838 by G. Mosander and first isolated in 1841 by G. Mosander. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1842 Discovery of Terbium Tb Terbium, atomic number 65, has a mass of 158.925 au. Terbium was first observed or predicted in 1842 by G. Mosander and first isolated in 1886 by J.C.G. de Marignac. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1842 Discovery of Erbium Er Erbium, atomic number 68, has a mass of 167.259 au. Erbium was first observed or predicted in 1842 by G. Mosander and first isolated in 1879 by T. Cleve. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1843 Gmelin's System L. Gmelin, Handbuch der chemie, 4th ed., Heidelberg, 1843, vol. 1, p. 457 (Many thanks to Carmen Giunta for the ref. update & link.) The early and important Gmelin formulation redrawn by Mark Leach with modern element symbols:
1844 Discovery of Ruthenium Ru Ruthenium, atomic number 44, has a mass of 101.07 au. Ruthenium was first isolated in 1844 by K. Claus. 1850 Elements Known in the Year 1850 Elements known in the year 1850, taken from this Wikipedia page: 1858 Cannizzaro's Letter Letter of Professor Stanislao Cannizzaro to Professor S. De Luca: Sketch of a Course of Chemical Philosophy given in the Royal University of Genoa, Il Nuovo Cimento, vol. vii. (1858), pp. 321-366. ![]() Many thanks to Carmen Giunta, Professor of Chemistry Emeritus, Le Moyne College who provided the information about, and link to, Cannizzaro's Letter. See a list of other classic chemistry papers.
From the Science History of Science Institute:
Mark Leach writes:
1860 Discovery of Cesium Cs Cesium (or caesium), atomic number 55, has a mass of 132.905 au. Cesium is a Group 1 element, and these are often referred to as the "alkali metals". Cesium was first observed or predicted in 1860 by R. Bunsen and R. Kirchhoff and first isolated in 1882 by C. Setterberg. 1860 Karlsruhe Congress The Karlsruhe Congress of 1860 was called so that European chemists could discuss a number of issues, including atomic weights. ![]() From Wikipedia (lightly edited):
Once enough elements had been discovered, and their atomic weights correctly deduced, the time was ripe to develop versions of the periodic table systems. These came 'thick & fast' after the Karlsruhe Congress.
1861 Discovery of Rubidium Rb Rubidium, atomic number 37, has a mass of 85.468 au. Rubidium is a Group 1 element, and these are often referred to as the "alkali metals". Rubidium was first observed, but not isolated in pure form, in 1861 by R. Bunsen and G. R. Kirchhoff. 1861 Discovery of Thallium Tl Thallium, atomic number 81, has a mass of 204.384 au. Thallium was first observed or predicted in 1861 by W. Crookes and first isolated in 1862 by C.-A. Lamy. 1862 Béguyer de Chancourtois' Vis Tellurique The French geologist , Alexandre-Émile Béguyer de Chancourtois was the first person to make use of atomic weights to produce a classification of periodicity. He drew the elements as a continuous spiral around a metal cylinder divided into 16 parts. The atomic weight of oxygen was taken as 16 and was used as the standard against which all the other elements were compared. Tellurium was situated at the centre, prompting vis tellurique, or telluric screw. Many thanks to Peter Wothers – and courtesy of the Master and Fellows of St Catharine's College, Cambridge – comes a high quality image of the original 1862 formulation. Click here, or on the image to enlarge: Watch Peter Wothers 'unravel' and show Prof. Martyn Poliakoff this first periodic table at 17min 50sec into the YouTube video below: Some more information: Chancourtois' original formulation includes elements in their correct places, selected compounds and some elements in more than one place. The helix was an important advance in that it introduced the concept of periodicity, but it was flawed. It has been suggested that Chancourtois called his formulation a telluric helix because tellurium is found in the middle. However, most elements are found as there their 'earths' – tellus, telluris – or oxides, which for a mineralogist would have been highly significant. The formulation was rediscovered in the 1889 (P. J. Hartog, "A First Foreshadowing of the Periodic Law" Nature 41, 186-8 (1889)), and since then it has appeared most often in a simplified form that emphasizes the virtues and eliminates its flaws. [Thanks to CG for this info.] See also:
A three dimensional models of the telluric helix: ![]() There are representations of the 1862 formulation at the School of Mines at ParisTech: 1862 Meyer's Periodic System In his book, The Periodic Table: A Very Short Introduction, Eric Scerri writes how Lothar Meyer devised a partial periodic tables consisting of 28 elements arranged in order of increasing atomic weight in which the elements were grouped into vertical columns according to their chemical valences: 1863 Discovery of Indium In Indium, atomic number 49, has a mass of 114.818 au. Indium was first observed or predicted in 1863 by F. Reich and T. Richter and first isolated in 1867 by T. Richter. 1864 Newlands' Octaves One of the first attempts at a periodic table that arranged the known elements by atomic weight and chemical property, was by John Newlands and is known as "Newlands Octaves". Newland noticed that if he broke up his list of elements into groups of seven starting a new row with the eighth element the first element in each of those groups had similar chemistry.
Philip Stewart's musical representation: ![]()
Read more about Newland's Octaves, including a commentary on the original papers in Carmen Giunta's Elements and Atoms: Case Studies in the Development of Chemistry. 1864 Odling's Table of Elements William Odling's table from: Q. J. Sci., 1864, 1, 642: 1864 Naquet's Families of Elements According to Naquet’s 1864 textbook, Principes de Chimie, F. Savy, Paris, (updated by Eric Scerri): 1866 Spectroscope Revelations From Scientific American in 1866, an article by Henry Draper concerning "The Spectroscope and Its Revelations". At the time there was no understanding how the spectra were generated but it was recognised that every element produced a unique spectrum. Over 35,000 stars are catalogued/identified by their "HD" [Henry Draper] numbers:
1867 Hinrichs' Programme of Atomechanics Gustavus Detlef Hinrichs' spiral "Programme of Atomechanics". Programm der Atomechanik oder die Chemie eine Mechanik de Pantome, Augustus Hageboek, Iowa City, IA (1867).
1868 Handwritten draft of the first version of Mendeleev's Periodic Table From of Bill Jensen, Curator of the Oesper Collection at the University of Cincinnati: 1868 Meyer's "Lost" Table of 1868 In his book, The Periodic Table: A Very Short Introduction, Eric Scerri writes how Lothar Meyer produced an expanded periodic system for his1868 textbook which contained 53 elements. Unfortunately, the table was misplaced by the publisher and was not appear until after his death in 1895: ![]() 1869 Mendeleev's Tabelle I Mendeleev [also spelled Mendeleyev in English] recounted in his diary:
1870 Meyer's Periodic Table. This is rather similar to the Mendeleev attempt at the same time. 1870 Baumhauer's Spiral
1870 Baker's Electronegativity Table Baker's electronegativity table of 1870 differs from Berzelius' listing of 1836 only by the addition of the newly discovered elements. Page 280 and ref. 5 from Bill Jensen's: Electronegativity from Avogadro to Pauling Part II: Late Nineteenth- and Early Twentieth-Century Developments, J. Chem. Educ., 80, 279-287 (2003): ![]() 1871 Mendeleev's Tabelle II Some versions of Mendeleev's Tabelle II of 1871. ![]() From the second volume of Mendeleev's textbook (click to enlarge): Notice that on the right hand side, there is an additional formulation: The two formulations above are discussed by Peter Wothers from the University of Cambridge with Sir Martyn Poliakoff, of the University of Nottingham, at 2:30 into the video below: Mendeleev's Tabelle II can be shown in semi-modern form with the 'missing' group 18 rare gases and the f-block elements: ![]()
An alternative version of Mendeleev's Tabelle II: ![]() 1871 Mendeleev's Predicted Elements In large part, the success of the Mendeleev's analysis can be attributed to the gaps which he predicted would contain undiscovered elements with predictable properties. Mendeleev named these unknown elements using the terms eka, dvi & tri (1, 2 & 3 from the ancient Indian language of Sanskrit). Mendeleev predictions include:
Image from van Spronsen 1871 Mendeleev's Periodic Table of 1871, redrawn by J.O. Moran, 2013Mendeleev's Periodic Table of 1871, redrawn by J.O. Moran, 2013, click here to see full size: 1872 Mendeléeff's Vertical Table (Q&Q's Spelling) Quam & Quam's review paper states:
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1872 Meyer's Spiral System Meyer's Spiral System of 1872 (from van Spronsen): 1875 Discovery of Gallium Ga Gallium, atomic number 31, has a mass of 69.723 au. Gallium was first isolated in 1875 by P. E. L. de Boisbaudran. 1875 Gibbes' Synoptical Periodic TableFrom page 127 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes: ![]() ![]()
1875 Concentric Ring Arrangement of WiikFrom page 133 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes: ![]() ![]()
1878 Discovery of Ytterbium Yb Ytterbium, atomic number 70, has a mass of 173.054 au. Ytterbium was first observed or predicted in 1878 by J.C.G. de Marignac and first isolated in 1906 by C. A. von Welsbach. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1878 Waechter's Numerical RegularitiesFrom page 136 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes: ![]() ![]()
1879 Discovery of Scandium Sc Scandium, atomic number 21, has a mass of 44.956 au. Scandium was first isolated in 1879 by F. Nilson. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1879 Discovery of Samarium Sm Samarium, atomic number 62, has a mass of 150.36 au. Samarium was first isolated in 1879 by P.E.L. de Boisbaudran. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1879 Discovery of Holmium Ho Holmium, atomic number 67, has a mass of 164.93 au. Holmium was first observed or predicted in 1878 by J.-L. Soret and first isolated in 1879 by T. Cleve. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1879 Discovery of Thulium Tm Thulium, atomic number 69, has a mass of 168.934 au. Thulium was first isolated in 1879 by T. Cleve. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1880 Discovery of Gadolinium Gd Gadolinium, atomic number 64, has a mass of 157.25 au. Gadolinium was first observed or predicted in 1880 by J. C. G. de Marignac and first isolated in 1886 by P.E.L. de Boisbaudran. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1880 Periodische Gesetzmässigkeit der Elemente nach Mendelejeff A lecture theatre sized periodic table, titled Periodische Gesetzmässigkeit der Elemente nach Mendelejeff, found at St Andrew's University, published and printed in Austria and dating from about from about 1880. Read more about this in The Guardian. Two YouTube videos about this PT: 1881 Spring's Diagram
1882 Bayley's Periodic System
1882 Brauner's Periodic Table Brauner's periodic table of 1882 with a homologous accommodation of the rare-earth elements, from Chemische Berichte, 15, 1882, p. 15-121: 1882 Bayley's AttemptFrom page 158 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes about Bayley: ![]() ![]()
1885 Discovery of Praseodymium Pr Praseodymium, atomic number 59, has a mass of 140.908 au. Praseodymium was first isolated in 1885 by Carl Auer von Welsbach. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1885 Discovery of Neodymium Nd Neodymium, atomic number 60, has a mass of 144.242 au. Neodymium was first isolated in 1885 by Carl Auer von Welsbach. Chronology of chemically the splitting of ceria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1885 Carnelley & The Periodic LawFrom page 172 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes: ![]() ![]() ![]()
1885 Klieber's Cosmochemical Periodic TableKlieber's qualitative synthesis of the general composition of celestial objects in the form of a plane periodic system following atomic numbers. His diagram is probably one of the earliest versions of a "cosmochemical periodic table". (The diagram below is clearly redrawn as it has a very modern style.) I.A. Kleiber, Zh. Russ. Fiziko-Khim. Obshch (St. Petersburg) 1885, 17, 147-171. ![]()
1885 von Richter's Periodic System of the ElementsFrom page 244 of A Text-book of Inorganic Chemistry by Victor von Richter, Published by Blakiston (US ed. in English, 1885). The full text (scanned) is available from archive.org. The first edition was published in 1874 in German. von Richter was was from the Baltic region, in the the Russian empire at the time. von Richter's work is almost certainly the first chemistry textbook based on the periodic system. Many (indeed most) modern Inorganic Chemistry texts follow this format, but NOT the Chemogenesis web book! von Richter, writes: ![]() ![]() ![]() ![]() ![]()
1886 Crookes' Periodic Table
1886 Discovery of Fluorine F Fluorine, atomic number 9, has a mass of 18.998 au. Fluorine exists as a pale yellow diatomic molecular gas, F2. It is the most electronegative and reactive of all elements: it which reacts with practically all organic and inorganic substances. Fluorine was first observed or predicted in 1810 by A.-M. Ampére and first isolated in 1886 by H. Moissan. 1886 Discovery of Germanium Ge Germanium, atomic number 32, has a mass of 72.63 au. Germanium was first isolated in 1886 by C. A. Winkler. 1886 Discovery of Dysprosium Dy Dysprosium, atomic number 66, has a mass of 162.5 au. Dysprosium was first isolated in 1886 by P.E.L. de Boisbaudran. Chronology of chemically the splitting of yttria (mixed oxides) into the pure rare-earth metals: From: CRC Handbook on the Physics and Chemistry of Rare Earths, Chapter 248. Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis 1886 Shepard's Natural ClassificationShepard's Natural Classification of the Elements, a spiral formulation with instructions for turning it into a three-dimensional table. From: Elements of Inorganic Chemistry, Descriptive and Qualitative (pp221), by J. H. Shepard, (1886), Boston MA, pub. D. C. Heath René Vernon writes:
![]() 1886 Reynolds' Method of Illustrating the Periodic LawReynolds, J. E. (1886). Note on a method of illustrating the periodic law. Chemical News, 54, 1–4 Ann E. Robinson comments:
![]() 1887 Flavitzky's Arrangement
1888 Stoney's Spiral Johnstone Stoney's Spiral, taken from A. E. Garrett's The Periodic Law (page 167, 1909 pub. D. Appleton And Company). The reference is given – page 167 – is: Phil. Mag. [6], 4, pp 411 et seq.; Proc. Roy. Soc., 1888, p115.
1888 Stoney's Spiral Periodic TableIn the Proceedings of the Royal Society of London, Series A, Containing Papers of a Mathematical and Physical Character, Volume 85, Issue 580, Aug 1911, p. 472, there is an article On Dr. Johnstone Stoney's Logarithmic Law of Atomic Weights, by Lord Rayleigh (who co-discovered argon in 1894), who writes :
Comment from Mark Leach:
![]() René Vernon writes:
1891 Mendeleev's Table In English A table, from Wikipedia, showing the periodicity of the properties of many chemical elements, from the first English edition of Dmitrii Mendeleev's Principles of Chemistry (1891, translated from the Russian fifth edition). It is worth noting that this 1981 formulation shows the presence of gallium and germanium that were not his original table. 1891 Wendt's Generation-Tree of the ElementsFrom page 244 of The Development of the Periodic Law by Venable, Francis Preston (1856-1934), Easton, Pa. Chemical Pub. Co (1896). The full text (scanned) is available from archive.org. Venable writes: ![]() ![]()
1892 Bassett's Vertical Arrangement Bassett's Vertical Arrangement is actually designed to be a three dimensional formulation. Quam & Quam's review paper states:
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1892 Bassett Dumb-Bell Form The Basset 'dumb-bell' formulation, ref. H. Basset, Chem. News, 65 (3-4), 19 (1892). The image is from Concept of Chemical Periodicity: from Mendeleev Table to Molecular Hyper-Periodicity Patterns E. V. Babaev and Ray Hefferlin, here. 1893 Rang's Periodic Arrangement of The Elements P.J.F. Rang's The Periodic Arrangement of the Elements, Chemical News, vol. 67, p. 178 (1893) Observing that that Rang's table has four 'groups': A, B, C & D, René Vernon writes:
1893 Nechaev's Truncated ConesRené Vernon (who found this formulation) writes:
![]() 1894 Discovery of Argon Ar Argon, atomic number 18, has a mass of 39.948 au. Argon is a noble gas. Argon was first isolated in 1894 by Lord Rayleigh and W. Ramsay. 1895 Retger's Periodic Table Periodic Table of Retgers with an intraperiodic accommodation of the rare earths. Retgers, J.W., 1895. Z. Phys. Chem. 16, 644: 1895 Thomsen's Systematic Arrangement of the Chemical Elements In 1895 the Danish thermochemist Hans Peter Jørgen Julius Thomsen proposed (Thomsen, J., 1895. Z. Anorg. Chem. 9, 190 & Chemical News, 72, 89–91, p. 90) a pyramidal/ladder representation. Notice how this formulation identifies the electropositive & electronegative elements with respect to the periodic table, thirty years before Linus Pauling. 1895 Discovery of Helium He Helium, atomic number 2, has a mass of 4.003 au. Helium is a noble gas, and is the second most abundant element in the universe after hydrogen. Helium was first observed or predicted in 1868 by P. Janssen and N. Lockyer from solar spectra, and first isolated in 1895 by W. Ramsay, T. Cleve, and N. Langlet. 1896 Richards' Classification of The Elements This is how the periodic table looked in 1896 in an article by Theodore Richards the pioneer of atomic weight measurement. Notice all those elements at the bottom that could not be classified, explicitly listed including He and Ar :
1896 Ramsay's Elements Arranged in the Periodic System From The Gases of the Atmosphere, The History of Their Discovery by William Ramsay (and from the Gutenberg Project.) The author writes pp 220-221:
1898 Crookes' vis generatrix Model of Crookes’ vis generatrix of 1898, built by his assistant, Gardiner. From: Proc. R. Soc. Lond. 63, 408. The vertical scale represents the atomic weight of the elements from H = 1 to Ur = 239. Missing elements are represented by a white circle. Similar elements appear underneath each other: 1898 Discovery of Neon Ne Neon, atomic number 10, has a mass of 20.18 au. Neon is a noble gas. It is present in the atmosphere, 1 part in 65000. Neon was first isolated in 1898 by W. Ramsay and W. Travers. 1898 Discovery of Krypton Kr Krypton, atomic number 36, has a mass of 83.798 au. Krypton is a noble gas. Krypton was first isolated in 1898 by W. Ramsay and W. Travers. 1898 Discovery of Xenon Xe Xenon, atomic number 54, has a mass of 131.293 au. Xenon is a noble gas. Xenon was first isolated in 1898 by W. Ramsay and W. Travers. 1898 Discovery of Polonium Po Polonium, atomic number 84, has a mass of 209 au. Radioactive element. Polonium was first observed or predicted in 1898 by P. and M. Curie and first isolated in 1902 by W. Marckwald. 1898 Discovery of Radium Ra Radium, atomic number 88, has a mass of 226 au. Radioactive element. Radium was first observed or predicted in 1898 by P. and M. Curie and first isolated in 1902 by M. Curie. 1899 Discovery of Radon Rn Radon, atomic number 86, has a mass of 222 au. Radon is a noble gas and it is a radioactive element. Radon was first observed or predicted in 1899 by E. Rutherford and R. B. Owens and first isolated in 1910 by W. Ramsay and R. Whytlaw-Gray.
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