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The INTERNET Database of Periodic Tables

There are thousands of periodic tables in web space, but this is the only comprehensive database of periodic tables & periodic system formulations. If you know of an interesting periodic table that is missing, please contact the database curator: Mark R. Leach Ph.D.

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Year:  1923 PT id = 1256

Deming's Periodic Table With Commentry by Vernon

René Vernon writes:

Deming's 1923 periodic table is credited with popularizing the 18-column form.

I now see Deming used different thickness sloping lines to represent the different degrees of similarity between the main groups and their corresponding transition metal groups.

When I plot up to 20 chemical properties v Z going down these options I get the following values for the average smoothness of the trendlines:

I would have thought the smoothness for the line between Li-Na and Cu would be < 70%, consistent with Deming’s dashed line. But the thickness of the line would depend on what Deming took into account when he drew it. The common wisdom about groups 1 and 11 is that their similarities are: "confined almost entirely to the stoichiometries (as distinct from the chemical properties) of the compounds in the +1 oxidation state." (Greenwood & Earnshaw 2002, p. 1177). Kneen et al. (1972, p. 521) say that, "the differences between the properties of the group IA and IB elements are those between a strongly and weakly electropositive metal." On this basis I follow Deming’s dashed line. I’ve appended some notes about Group 1 and Group 11.

I have [calculated] a smoothness for C-Si-Ti-Zr-Hf of 86% versus 70% for C-Si-Ge-Sn-Pb. Since Ti shows some transition metal chemistry but not C-Si, it is perhaps plausible to keep C-Si-Ge-Sn-Pb together (as Deming did ).

Deming was a smart author. Nigh on a century later and the metrics check out.

More about group 1 and group 11

There may be a little more to the relationship between Li-Na & Cu-Ag-Au, than is ordinarily appreciated. For example:


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