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  Web Book Home Page | Chemogenesis Main Index Foreword:  Chemogenesis & Chemical Education Part I   Atoms | Elements | Periodic Tables 1.1  Introduction to Chemogenesis 1.2  Nucleosynthesis of The Elements 1.3  The Segrè Chart 1.4  Quantum Numbers to Periodic Tables 1.5  The Periodic Table: What Is It Showing? 1.6  The INTERNET Database of Periodic Tables 1.7  Periodicity Part II   Structure | Bonding | Material Type 2.1  Mono-Bond Typed Binary Compounds 2.2  Binary Compound Synthlet 2.3  Electronegativity 2.4  van Arkel-Ketelaar Triangles of Bonding 2.5  Tetrahedra of Structure, Bonding & Material Type 2.6  Structure, Bonding & Material Synthlet 2.7  The Classification of Matter: Chemical Stuff Part III   Interactions | Reactions | Mechanisms 3.1  The Chemogenesis Analysis: An Overview 3.2  Lewis and Brønsted Models of Acidity 3.3  The Hard Soft [Lewis] Acid Base Principle 3.4  Main Group Elemental Hydrides 3.5  Five Hydrogen Probe Experiments 3.6  Congeneric Dots, Series & Planars 3.7  Quantifying Congeneric Behaviour 3.8  Ligand Replacement Congeneric Series 3.9  Congeneric Array Interactions 3.10  Emergence of Organic Chemistry 3.11  Congeneric Array Database 3.12  The Five Reaction Chemistries 3.13  Lewis Acids & Lewis Bases: A New Analysis 3.14  The Lewis Acid/Base Interaction Matrix 3.15  Patterns in Reaction Chemistry Poster 3.16  Lewis Acid/Base Interaction Matrix Database 3.17  Nucleophiles, Bases & The Fluoride Ion 3.18  Redox Chemistry 3.19  Redox Chemistry Synthlet 3.20  Radical Chemistry 3.21  Diradical Chemistry 3.22  Photochemistry 3.23  Species/Species Interactions 3.24  The Simplest Mechanistic Step: STAD 3.25  Unit & Compound Mechanistic Steps 3.26  The Mechanism Matrix 3.27  Addition To A Double Bond Synthlet 3.28  Pericyclic Reaction Chemistry Part IV   Chemical Theory 4.1  Why Do Chemical Reactions Occur? 4.2a  Thermochemistry: List Reactions Synthlet 4.2b  Thermochemistry: Play With Reaction Synthlet 4.2c  Thermochemistry: Bulid A Reaction Synthlet 4.3  Timeline of Structural Theory 4.4  Modern Lewis Theory 4.5  Valence Shell Electron Pair Repulsion: VSEPR 4.6  Diatomic Species by Molecular Orbital Theory 4.7  Polyatomic Species: Molecular Orbitals 4.8  Organic π-Systems 4.9  Functional Group Database Part V   Complexity & Emergence 5.1  Chemistry & Complexity: Systems 5.2  Linear Chemistry Systems 5.3  Chemical Systems Prone to Complexity Part VI   Extras 6.1  Chemogenesis Videos 6.2  Chemical Thesaurus Reaction Chemistry Database 6.3  Paper: Chemogenesis 6.4  Paper: Electronegativity as a Basic Elemental Property (FoC) 6.5  Workshop: What is Chemistry? 6.6  Paper: Scientific laws, Dalton’s postulates, chemical reactions
          and Wolfram’s NKS (FoC) 6.7  Literature References & Further Reading

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The INTERNET Database of Periodic Tables

There are thousands of periodic tables in web space, but this is the only comprehensive database of periodic tables & periodic system formulations. If you know of an interesting periodic table that is missing, please contact the database curator: Mark R. Leach Ph.D. The database holds information on periodic tables, the discovery of the elements, the elucidation of atomic weights and the discovery of atomic structure (and much, much more).

Pauli and The Exclusion Principle

Pauli, W. Über den Zusammenhang des Abschlusses der Elektronengruppen im Atom mit der Komplexstruktur der Spektren. Zeitschrift für Physik, 31, 765–783 (1925).

Wikipedia:

"Wolfgang Pauli was an Austrian–Swiss theoretical physicist and a pioneer of quantum mechanics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics 'for the discovery of the Exclusion Principle, also called the Pauli Principle'. The discovery involved spin theory.

"The Pauli exclusion principle (German: Pauli-Ausschlussprinzip) states that two or more identical particles with half-integer spins (i.e. fermions) cannot simultaneously occupy the same quantum state within a system that obeys the laws of quantum mechanics. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925 for electrons, and later extended to all fermions with his spin–statistics theorem of 1940.

"In the case of electrons in atoms, the exclusion principle can be stated as follows: in a poly-electron atom it is impossible for any two electrons to have the same two values of all four of their quantum numbers, which are: n, the principal quantum number; ℓ, the azimuthal quantum number; m_ℓ, the magnetic quantum number; and m_s, the spin quantum number.

"If two electrons reside in the same orbital, then their values of n, ℓ, and m_ℓ are equal. In that case, the two values of m_s (spin) pair must be different. Since the only two possible values for the spin projection ms are +1/2 and –1/2, it follows that one electron must have m_s = +1/2 and one m_s = –1/2.

"To preserve the conservation of energy in beta decay, Pauli proposed the existence of a small neutral particle, dubbed the neutrino by Enrico Fermi, in 1930. Neutrinos were first detected in 1956. "

© Mark R. Leach Ph.D. 1999 –

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