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  Web Book Home Page | Chemogenesis Main Index Foreword:  Chemogenesis & Chemical Education Part I   Atoms | Elements | Periodic Tables 1.1  Introduction to Chemogenesis 1.2  Nucleosynthesis of The Elements 1.3  The Segrè Chart 1.4  Quantum Numbers to Periodic Tables 1.5  The Periodic Table: What Is It Showing? 1.6  The INTERNET Database of Periodic Tables 1.7  Periodicity Part II   Structure | Bonding | Material Type 2.1  Mono-Bond Typed Binary Compounds 2.2  Binary Compound Synthlet 2.3  Electronegativity 2.4  van Arkel-Ketelaar Triangles of Bonding 2.5  Tetrahedra of Structure, Bonding & Material Type 2.6  Structure, Bonding & Material Synthlet 2.7  The Classification of Matter: Chemical Stuff Part III   Interactions | Reactions | Mechanisms 3.1  The Chemogenesis Analysis: An Overview 3.2  Lewis and Brønsted Models of Acidity 3.3  The Hard Soft [Lewis] Acid Base Principle 3.4  Main Group Elemental Hydrides 3.5  Five Hydrogen Probe Experiments 3.6  Congeneric Dots, Series & Planars 3.7  Quantifying Congeneric Behaviour 3.8  Ligand Replacement Congeneric Series 3.9  Congeneric Array Interactions 3.10  Emergence of Organic Chemistry 3.11  Congeneric Array Database 3.12  The Five Reaction Chemistries 3.13  Lewis Acids & Lewis Bases: A New Analysis 3.14  The Lewis Acid/Base Interaction Matrix 3.15  Patterns in Reaction Chemistry Poster 3.16  Lewis Acid/Base Interaction Matrix Database 3.17  Nucleophiles, Bases & The Fluoride Ion 3.18  Redox Chemistry 3.19  Redox Chemistry Synthlet 3.20  Radical Chemistry 3.21  Diradical Chemistry 3.22  Photochemistry 3.23  Species/Species Interactions 3.24  The Simplest Mechanistic Step: STAD 3.25  Unit & Compound Mechanistic Steps 3.26  The Mechanism Matrix 3.27  Addition To A Double Bond Synthlet 3.28  Pericyclic Reaction Chemistry Part IV   Chemical Theory 4.1  Why Do Chemical Reactions Occur? 4.2a  Thermochemistry: List Reactions Synthlet 4.2b  Thermochemistry: Play With Reaction Synthlet 4.2c  Thermochemistry: Bulid A Reaction Synthlet 4.3  Timeline of Structural Theory 4.4  Modern Lewis Theory 4.5  Valence Shell Electron Pair Repulsion: VSEPR 4.6  Diatomic Species by Molecular Orbital Theory 4.7  Polyatomic Species: Molecular Orbitals 4.8  Organic π-Systems 4.9  Functional Group Database Part V   Complexity & Emergence 5.1  Chemistry & Complexity: Systems 5.2  Linear Chemistry Systems 5.3  Chemical Systems Prone to Complexity Part VI   Extras 6.1  Chemogenesis Videos 6.2  Chemical Thesaurus Reaction Chemistry Database 6.3  Paper: Chemogenesis 6.4  Paper: Electronegativity as a Basic Elemental Property (FoC) 6.5  Workshop: What is Chemistry? 6.6  Paper: Scientific laws, Dalton’s postulates, chemical reactions
          and Wolfram’s NKS (FoC) 6.7  Literature References & Further Reading

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The INTERNET Database of Periodic Tables

There are thousands of periodic tables in web space, but this is the only comprehensive database of periodic tables & periodic system formulations. If you know of an interesting periodic table that is missing, please contact the database curator: Mark R. Leach Ph.D. The database holds information on periodic tables, the discovery of the elements, the elucidation of atomic weights and the discovery of atomic structure (and much, much more).

Periodic Tables from the year 1858 :

Cannizzaro's Letter or Sunto

Letter of Professor Stanislao Cannizzaro to Professor S. De Luca: Sunto di un corso di filosofia chimica (Sketch of a Course of Chemical Philosophy) given in the Royal University of Genoa, Il Nuovo Cimento, vol. vii. (1858), pp. 321-366.

Many thanks to Carmen Giunta, Professor of Chemistry Emeritus, Le Moyne College who provided the information about, and link to, Cannizzaro's Letter. See a list of other classic chemistry papers.

Read the full letter/paper, in English translation, here. (The Italian version is here.)

Cannizzaro writes:

"I believe that the progress of science made in these last years has confirmed the hypothesis of Avogadro, of Ampère, and of Dumas on the similar constitution of substances in the gaseous state; that is, that equal volumes of these substances, whether simple or compound, contain an equal number of molecules: not however an equal number of atoms, since the molecules of the different substances, or those of the same substance in its different states, may contain a different number of atoms, whether of the same or of diverse nature."

From the Science History of Science Institute:

"In 1858 Cannizzaro outlined a course in theoretical chemistry for students at the University of Genoa,where he had to teach without benefit of a laboratory. He used the hypothesis of a fellow Italian, Amedeo Avogadro, who had died just two years earlier, as a pathway out of the confusion rampant among chemists about atomic weights and the fundamental structure of chemical compounds."

Mark Leach writes:

"Before a periodic table of the chemical elements – which orders the elements by atomic weight and then groups them by property – could be developed it was necessary to know the atomic weight values. However, to deduce the atomic weights was a problem as it was necessary to know the ratios of how the elements combined, the stoichiometry.

"Tables of atomic weight data by Dalton (1808), Wollaston (1813), Daubeny (1831) and Kopp & Will (1858) show progress, but the 1858 Cannizzaro letter was the first where the atomic weight data is more or less both complete and accurate, thus removing stiochiometric errors.

"I have extracted the element atomic weight data from the paper, and given the % error with respect to modern atomic weight/mass data. Only titanium is significantly out! It is clear that Cannizzaron knew that hydrogen, nitrogen, oxygen, chlorine, bromine & iodine existed as diatomic molecules."

Below is a list of the elements showing which ones were included by Cannizzaro and which one were ommitted (because they had not been discovered) or are strangely missing. Odd ommissions (to the modern eye) include: Lithium, Beryllium, Cobalt, Nickel, Palladium, Tungsten and Gold.

Annual Report on the Progress of Chemistry and Related Areas of Other Sciences 1858

Jahresbericht über die Fortschritte der Chemie und verwandter Theile anderer Wissenschaften. (Annual Report on the progress of chemistry and related areas of other sciences.) HathiTrust Index scanned reports 1847-1910.

The 1858 table of data is here.

Mark Leach writes:

"Every year the annual report started with a list of the known chemical elements and their atomic weights, however, to the modern eye there were many systermatic errors. For example, oxygen (Sauerstoff) is given as having a weight of 8 which would have caused – due to the importance of oxides – other atomic weights to be out by a factor of 2 or 3. Once a list of correct atomic weights was known, it would be possible to construct a periodic table of the elements.

"In 1858 the Cannazzario letter gave more correct list of atomic weights and corrected the numerous stoichiometric errors that plagued chemistry at the time. Over the years from 1858 to 1873 the entries in the annual report gradually adopted the Cannazzario logic."

• Didym D = 48 was actually a mixture of rare earth elements.
• Norium No is a discredited claim to be what is now known as hafnium.
• The missing elements had yet to be discovered.
• Be is shown as 4.7 and 7.0
• Si is shown as 14 and 21
• Zr is shown as 22.4 and 33.6

Thanks to René and Mario Rodriguez for the tip!

© Mark R. Leach Ph.D. 1999 –

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